Perovskites: Structure and Growth Control of Organic–Inorganic Halide Perovskites for Optoelectronics: From Polycrystalline Films to Single Crystals (Adv. Sci. 4/2016)

Structure and Growth Control of Organic–Inorganic Halide Perovskites for Optoelectronics: From Polycrystalline Films to Single Crystals

Recently, organic-inorganic halide perovskites have sparked tremendous research interest because of their ground-breaking photovoltaic performance. The crystallization process and crystal shape of perovskites have striking impacts on their optoelectronic properties. Polycrystalline films and single crystals are two main forms of perovskites. Currently, perovskite thin films have been under inte...

Singe-crystal microplates of two-dimensional organic-inorganic lead halide layered perovskites for optoelectronics

Metal halide perovskite light emitters.

Twenty years after layer-type metal halide perovskites were successfully developed, 3D metal halide perovskites (shortly, perovskites) were recently rediscovered and are attracting multidisciplinary interest from physicists, chemists, and material engineers. Perovskites have a crystal structure composed of five atoms per unit cell (ABX3) with cation A positioned at a corner, metal cation B at t...

Post-synthetic halide conversion and selective halogen capture in hybrid perovskites.

Reaction with halogen vapor allows us to post-synthetically exchange halides in both three- (3D) and two-dimensional (2D) organic-inorganic metal-halide perovskites. Films of 3D Pb-I perovskites cleanly convert to films of Pb-Br or Pb-Cl perovskites upon exposure to Br2 or Cl2 gas, respectively. This gas-solid reaction provides a simple method to produce the high-quality Pb-Br or Pb-Cl perovski...

Controllable lasing performance in solution-processed organic-inorganic hybrid perovskites.

Solution-processed organic-inorganic perovskites are fascinating due to their remarkable photo-conversion efficiency and great potential in the cost-effective, versatile and large-scale manufacturing of optoelectronic devices. In this paper, we demonstrate that the perovskite nanocrystal sizes can be simply controlled by manipulating the precursor solution concentrations in a two-step sequentia...